Coordination nano space as stage of hydrogen ortho para conversion

Please use this identifier to cite or link to this item: https://lib.hpu.edu.vn/handle/123456789/22428

Title:	Coordination nano space as stage of hydrogen ortho para conversion
Authors:	Kosone, Takashi Hori, Akihiro Nishibori, Eiji
Keywords:	Chemistry Chemical physics Crystallography Spectroscopy Hydrogen storage porous coordination polymer Structure of absorbed H2 Ortho–para conversion
Issue Date:	2015
Abstract:	The ability to design and control properties of nano-sized space in porous coordination polymers (PCPs) would provide us with an ideal stage for fascinating physical and chemical phenomena. We found an interconversion of nuclear-spin isomers for hydrogen molecule H2 adsorbed in a Hofmann-type PCP, {Fe(pz)[Pd(CN)4]} (pz=pyrazine), by the temperature dependence of Raman spectra. The ortho (o)–para (p) conversion process of H2 is forbidden for an isolated molecule.
URI:	https://lib.hpu.edu.vn/handle/123456789/22428
Appears in Collections:	Education

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