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https://lib.hpu.edu.vn/handle/123456789/21905| Title: | Difluoromethanesulfonyl hypervalent iodoniumylides for electrophilic difluoromethylthiolation reactions under copper catalysis |
| Authors: | Arimori, Sadayuki Matsubara, Okiya Takada, Masahiro |
| Keywords: | Organic chemistry Synthetic Chemistry Organometallic chemistry Difluoromethylthiolation Hypervalent Iodoniumylide Carbene Sulfur Fluorine |
| Issue Date: | 2016 |
| Abstract: | Difluoromethanesulfonyl hypervalent iodonium ylides 2 were developed as electrophilic difluoromethylthiolation reagents for a wide range of nucleophiles. Enamines, indoles, β-keto esters, silyl enol ethers and pyrroles were effectively reacted with2affording desired difluoromethylthio (SCF2H)-substituted compounds in good to high yields under copper catalysis. |
| URI: | https://lib.hpu.edu.vn/handle/123456789/21905 |
| Appears in Collections: | Education |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 0271_Difluoromethanesulfonyl.pdf Restricted Access | 764.67 kB | Adobe PDF |  View/Open Request a copy |
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